It's most likely caused by the pad material, or the discs have become glazed because of the pad material. Howard Reynolds of Race Brakes recommends TRW, which is a commonly found brand of pad or his own Race Brakes brand pads.
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IT IS hard to diagnose problems like this without seeing the car and experiencing the problem first-hand. But the fact that changing the fuel pump hasn't fixed anything suggests its not a supply problem. I would look for an electrical fault, possibly even a loose or faulty connection. It could even be a problem with the ECU.
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The Rover 75 2001 prices range from $3,080 for the basic trim level Sedan Club to $6,380 for the top of the range Sedan Connoisseur Se.